Chemical properties of flooded soils

Rice is predominately grown under flooded conditions. This is unique for crop cultivation and has a big influence on the availability of nutrients.

The following chemical changes take place and influence nutrient availability.

Influence of flooding on nutrient availability

Nutrient Availability
P Desorption of P held by Fe3 oxides
K K Exchangable K is displaced from cation exchange sites into soil solution due to competition for mineral sites from Mn2+and Fe2. Flooding of soils containing K-fixing minerals may increase K fixation.
S Reduction of SO42 to elemental S and sulfide
Zn

Formation of Zn(OH)2 in acid soils and ZnS in sodic and calcareous soils. 

Formation of Zn-phosphates.

Mg Tends to increase due to displacement of exchangable Mg2+ by Fe2+.
Ca Tends to increase due to displacement of exchangable Ca2+ by Fe2+.
Fe Fe3+ oxides are reduced to plant-available Fe2+
Mn Mn4+ oxides are reduced to plant-available Mn2+
B Availability decreases in acid soils and increases in alkaline soils

Also Nitrogen is influenced by flooding. The picture below shows which N form is mainly present in flooded soil without fertilizer application.